Faculty of Science Engineering and Technology: Recent submissions
Now showing items 81-100 of 240
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Synthesis and characterization of half-sandwich ruthenium(II) complexes with N-alkyl pyridyl-imine ligands and their application in transfer hydrogenation of ketones
(2016-08-24)A series of new arene ruthenium(II) complexes were prepared by reaction of ruthenium(II) precursors of the general formula [(η6-arene)Ru(μ-Cl)Cl]2 with N,N′-bidentate pyridyl-imine ligands to form complexes of the type ... -
Effect of Human Activities and Seasonal Variation on Water Quality of Nkenye (Chikuu) Stream in Chuka, Kenya
(2013-01)Composite water and sediment samples were taken from Nkenye stream at five different sampling stations during wet and dry seasons. Water quality parameters were analyzed using standard methods to ascertain ... -
Spectrophotometric Determination of Iron(III) by New Analytical Reagents Derived from Coupling Arylhydroxylamine and Aryldiazonium Salt
(2012)A highly sensitive and selective spectrophotometric method is developed for the determination of iron(III) in aqueous solution with hydroxytriazenes. In this work, the effect of pH variation, the composition of the complex ... -
A study of new half-sandwich Osmium(II) complexes with bidentate N,N-chelating ligands and their use in the transfer hydrogenation of ketones
(2016-11)The reaction of appropriate N,N-bidentate ligands with the [(η6-p-cymene)Os(μ-Cl)Cl]2 dimer, followed by metathesis reaction with NH4PF6, gave the new osmium(II) arene complex salts [(η6-p-cymene)OsCl(C5H4N-2-CH=N-R]PF6, ... -
Physico-Chemical Analysis of Ground Water from Kihara Division, Kiambu County, Kenya
(2012)Water quality is an index of health and is one of the areas of major concern to environmentalists, since industrialization, urbanization and modern agricultural practices have a direct impact on the water resources. Borehole ... -
Geochemical and Mineralogical Characteristics of Geophagic Materials from Kiambu, Kenya
(Modern Scientific Press Company, Florida, USA, 2012-09)Geophagia is the deliberate consumption of soil and clay. The practice of geophagia is due to reasons of culture, medicinal, religious and mineral deficiency. Geophagy is widespread among pregnant and ... -
Synthesis, Characterization, Electrochemical and Antibacterial Studies of Half-sandwich Ru(II) Complex of 4-fluoro-N-(2-pyridiylmethylene)-aniline Schiff Base
(2018-10)The 4-fluoro-N-(2-pyridiylmethylene)-aniline Schiff base ligand (L) and its complex has been synthesized and successfully characterized by 1H NMR, elemental analysis, UV/VIS spectroscopy. Electrochemical properties were ... -
Synthesis and characterization of water-soluble arene- ruthenium complexes and their application in biphasic olefin oxidation
(2018-12-25)New water-soluble complexes [(η6-C6H6)RuCl(C5H4N-2-CH = N-R)]Cl (1) (with R = 4-hydroxymethylphenyl (a), 2,4-dichlorophenyl (b), 2-fluorophenyl (c), 3-carboxyphenyl (d)) have been synthesized by reacting [(η6-C6H6)Ru(μ-Cl)Cl]2 ... -
Crystal structure of chlorido-(η6-p-cymene)-(N- (2-fluorophenyl)-1-(pyridin-2-yl) methanimine-κ2N, N′) ruthenium (II)–acetone (1/1), C22H23ClN2F7OPRu.
(2010-01)C 22 H 23 ClN 2 F 7 OPRu, monoclinic, P 2 1 / c (no. 14), a = 7.30480(10) Å, b = 12.9540(3) Å, c = 28.7076(6) Å, β = 96.6990(10)°, V = 2697.95(9) Å ³ , Z = 4, Rgt ( F ) = 0.0196, wRref ( F² ) = 0.0479, T = 100(2) K. -
Crystal structure of chlorido-(η5-pentamethylcyclopenta dienyl)-((bis-pyrazol-1-yl) methane-κ2N, N′) rhodium (III) hexafluorophosphate
(2019-11-13)C17H23ClN4RhF6P, monoclinic, P21/c (no. 14), a = 10.6954(2) Å, b = 15.3868(3) Å, c = 12.6130(2) Å, β = 90.5590(10)°, V = 2075.60(7) Å3, Z = 4, Rgt(F) = 0.0296, wRref(F2) = 0.0727, T = 100(2) K. -
Synthesis and insecticidal activities of some selected hydroxytriazenes
(2011-10)Eight hydroxytriazenes were synthesized and then subjected to spot tests. The composition of these hydroxytriazenes was analyzed using elemental analysis and their physical characteristics like melting point, crystal shape ... -
Selective conversion of fructose to methyl levulinate using sulphated
(2015-01)Mesoporous sulfated-metal oxides and mixed-metal oxides prepared by a facile coprecipitation method employing titanium oxysulfate–sulfuric acid complex as a precursor of both titanium and sulfate are highly active and ... -
Antibacterial and antifungal activities of novel hydro
(2012)In a search for new leads potent antimicrobial agents, an array of novel hydroxytriazenes i-xi were synthesized and characterized through their melting point, crystal shape, colour and elemental analysis. ... -
Crystal structure of η6-p-cymene-iodido- (N-isopropyl-1-(pyridin-2-yl) methanimine-κ2N, N′) ruthenium (II) hexafluorophosphate (V), C19H26IN2F6Ru
(2019-12-07)C19H26IN2F6Ru, triclinic, P1̄ (no. 2), a = 9.240(2) Å, b = 10.019(3) Å, c = 12.689(3) Å, α = 78.921°, β = 81.596(10)°, γ = 83.654°, V = 1136.30(5) Å3, Z = 2, Rgt(F) = 0.0174, wRref(F2) = 0.0440, T = 173 K. -
Synthesis, characterization, and antimicrobial studies of half-sandwich η6-toluene ruthenium complexes with N,N′-bidentate ligands
(Taylor and Francis, 2020-07-29)Nine new complexes [(η6-C6H5-CH3)RuLCl]+(PF6)ˉ (where L = N,N′-bidentate ligand; (C5H4NCH = N-Ar) where Ar = 4-methylphenyl (C20H20ClF6N2PRu, 1); 3,4-dimethylphenyl (C21H22ClF6N2PRu, 2); 2,4,6-trimethylphenyl (C21H24ClF6N2PRu, ... -
Chemical And Mineralogical Analysis of Geophagic Materials Consumed By Pregnant Women In Eastern Nairobi And Nyanza Provinces In Kenya
(2011)Geophagy is the purposeful or deliberate consumption of Earth and clay deposits by animals, including man. It is a special type of pica, which is defined as the craving and subsequent consumption of non-food substances. ... -
Synthesis and Insecticidal activities of some selected hydroxytriazenes
(2012-10)Eight hydroxytriazenes were synthesized and then subjected to spot tests. The composition of these hydroxytriazenes was analyzed using elemental analysis and their physical characteristics like melting point, crystal shape ... -
Geochemical and Mineralogical Characteristics of Geophagic Materials from Kiambu, Kenya
(2012)Geophagia is the deliberate consumption of soil and clay. The practice of geophagia is due to reasons of culture, medicinal, religious and mineral deficiency. Geophagy is widespread among pregnant and ... -
Status of Water Quality of Naka River in Meru South, Kenya.
(2012)The study was carried out for a period of two seasons (wet and dry) in a year. The physicochemical, bacteriological parameters of water and trace metals in sediment samples were evaluated at ... -
Investigation Of Physicochemical and Bacteriological Characteristics Of Water Samples From Irigu River Meru South, Kenya
(2012-11)Physicochemical and bacteriological parameter levels of river Irigu were investigated during wet and dry season in order to assess the degree of pollution .The results obtained were compared with WHO standards for drinking ...